Microwave assisted Pd(OAc)2-catalyzed chemoselective reduction of aryl α,β-unsaturated esters with triethylsilane

Authors

  • Anamika Srivastava Department of Chemistry, Banasthali Vidyapith, Banasthali-304022 (Rajasthan), India.
  • Anshu Kumar Sinha Department of Applied Chemistry, Amity School of Applied Sciences, Amity University Haryana, Gurugram-122413 (Haryana), India.
  • Chandra Mohan Srivastava Centre for Polymer Technology, Amity School of Applied Sciences, Amity University Haryana, Gurugram-122413 (Haryana), India.
  • Gyandshwar Kumar Rao Department of Applied Chemistry, Amity School of Applied Sciences, Amity University Haryana, Gurugram-122413 (Haryana), India.
  • Manish Srivastava Department of Chemistry, Banasthali Vidyapith, Banasthali-304022 (Rajasthan), India.
  • Pooja Rawat Department of Applied Chemistry, Amity School of Applied Sciences, Amity University Haryana, Gurugram-122413 (Haryana), India.
  • Renuka Yadav Department of Applied Chemistry, Amity School of Applied Sciences, Amity University Haryana, Gurugram-122413 (Haryana), India.
  • Varun Rawat Department of Applied Chemistry, Amity School of Applied Sciences, Amity University Haryana, Gurugram-122413 (Haryana), India.
  • Yogesh Kumar Department of Applied Chemistry, Amity School of Applied Sciences, Amity University Haryana, Gurugram-122413 (Haryana), India.
Abstract:

< p>In this communication, we have reported that the Pd(OAc)2–Et3SiH-DMF system promotes the microwave-assisted chemoselective reduction of aryl α,β-unsaturated esters in good yields. The protocol affords a convenient reduction of aryl-conjugated double bonds even in presence of other functional groups like esters, phenols, and ethers.

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Journal title

volume 10  issue 3

pages  203- 208

publication date 2020-09-01

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